Light-Propelled Super-Hydrophobic Sponge Motor and its Application in Oil-Water Separation.

Self-propelled separation materials, that is, motor, are one of the keys to realizing smart oil-water separation. Although three-dimensional sponges such as commercial melamine sponge (MS) exhibit excellent oil-water separation ability, they cannot move by themselves on water. Aiming at solving this problem, a polydimethylsiloxane (PDMS) and molybdenum disulfide (MoS2) modified MS motor (PDMS@MS/MoS2) with an asymmetric multilayer structure was prepared, in which the photothermal layer MoS2 provided the propelling force for the motor under infrared light irradiation, and the middle layer PDMS was used as the superhydrophobic modified agent and adhesive agent between commercial MS and MoS2 powder. PDMS coated MS (PDMS@MS) as the superhydrophobic layer showed good superhydrophobic ability (153.1°) and oil-water separation capacity (52.33 g/g to liquid paraffin). Furthermore, the introduction of MoS2 made the speed of the sponge motor reach 8.27 mm s-1 with a removal quantity of 12.20 g/g for cyclohexane. After recycling 8 times, the contact angle, cyclohexane capturing amount, and average velocity of the motor were 150.3°, 11.40 g/g, and 8.41 mm/s, respectively. Meanwhile, PDMS@MS/MoS2 kept a similar light-propelling velocity (∼8 mm) at different pH values and in simulated seawater, demonstrating that the light-propelling motor possessed a good cycle and practical performance, which provides a possibility for the directional light propulsion of a sponge motor in oil-water separation.

Aggregation-induced emission monomer-based fluorescent molecularly imprinted poly(ionic liquid) synthesized by a one-pot method for sensitively detecting 4-nitrophenol.

An aggregation-induced emission monomer-based fluorescent molecularly imprinted poly(ionic liquid) (AIE-FMIPIL) was synthesized for the first time with an AIE probe 4-(1,2,2-triphenylvinyl)phenyl acrylate (TPE), and an ionic liquid as dual functional monomers, and an ionic liquid as cross-linker. AIE-FMIPIL displayed a sphere-like shape and its average diameter was 410 nm. The absolute quantum yields of TPE and AIE-FMIPIL were 9.23% and 12.61%, respectively. The synergetic effect of TPE in the AIE-FMIPIL framework contributed to the higher quantum yield of AIE-FMIPIL. 4-Nitrophenol (4-NP) efficiently quenched AIE-FMIPIL with high fluorescence based on the Förster resonance energy transfer mechanism. The synthesized AIE-FMIPIL sensor was highly sensitive for 4-NP detection (linear range, 0.02-1.5 µM) in the optimal detection condition, with a low detection limit of 10 nM (S/N = 3). AIE-FMIPIL showed increased sensitivity and quenching efficiency compared with AIE-FMIP comprising a traditional monomer and cross-linker. AIE-FMIPIL exhibited selective binding to 4-NP because of the imprinted sites. AIE-FMIPIL was adopted to detect 4-NP in environmental samples.